One of the key goals of astrochemistry is to simulate astrophysical and planetary conditions in the laboratory in order to understand physical and chemical processes that occur in those environments. Astrophysical and planetary conditions range from ultracold molecular clouds to hot exoplanetary atmospheres, covering gas, liquid, and solid phases at ultrahigh vacuum to megabar pressures, radiation from stars, cosmic rays, and local magnetospheric radiation environments, requiring broad range of researchers to contribute to the field of astrochemistry. Our contribution has been in two fields: (a) physics and chemistry of ice and organics in radiation environments; (b) simulations of exoplanet atmospheres simulating photochemistry at high-temperatures in the gas-phase.
At the Ice Spectroscopy Laboratory (ISL) at JPL, we conducted Lya UV-photolysis of astrophysical ices and showed that the formation of molecules of life such as HCN, formamide, etc., demonstrating that some of the key organic molecules needed for the origin of life could have already formed in the interstellar ice grains [1]. Significant new experimental and observational data are needed to close the knowledge gaps in this area of research, which is critical to test the hypothesis that early bombardment from comets and asteroids about 4 billion years ago would have brought water and organic molecules to Earth kickstarting origin of life on Earth [2-4].
Further research activities in our lab over the past decade simulating radiation processing of planetary ices - atmospheric and surface - will be discussed. Our most recent work on simulating photochemistry of high-temperature exoplanet atmospheres will also be discussed.
Acknowledgment: This work was carried out at the Jet Propulsion Laboratory, California Institute of Technology, under a contract with the National Aeronautics and Space Administration (NASA). Funding from NASA through DDAP, HW, NFDAP, SSW, and XRP programs is acknowledged.
References:
1. Henderson, B.L. and M.S. Gudipati, Astrophysical Journal, 2015. 800(1): p. 66.
2. Greenberg, J.M., Instruments, Methods, and Missions for the Investigation of Extraterrestrial Microorganisms, ed. R.B. Hoover. Vol. 3111. 1997. 226-237.
3. Huebner, W.E. and D.C. Boice, Origins of Life and Evolution of the Biosphere, 1992. 21(5-6): p. 299-315.
4. Altwegg, K., et al., Science Advances, 2016. 2(5).